I'm not sure I fully understand your question.
But Dictionaries expect its elements to respond to #key/#value messages, and in the case of Pharo Dictionary is tightly bound to the Association class (and the #-> selector), so there is no way to subclassify Dictionary and specify the class of its elements.
Otherwise you could subclassify Dictionary and have its elements to be instances of "MinipediaLanguage",��that is polymorphic with Association but have language/titles instead of key/value.
I don't see the need for it, though.