I missed the start of the thread but I've been using PostgreSQL and Pharo for quite a while on Windows XP (both PostgreSQL & Pharo).  So far, Pharo is rock-solid with ODBC, at least on WinXP !
 
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Benoit St-Jean
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A standpoint is an intellectual horizon of radius zero.
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From: "Schwab,Wilhelm K" <bschwab@anest.ufl.edu>
To: "Pharo-project@lists.gforge.inria.fr" <Pharo-project@lists.gforge.inria.fr>
Sent: Wed, April 13, 2011 7:00:13 PM
Subject: [Pharo-project] PostgresSQL - ODBC

Hello all,

I have been successful in using unixODBC and a Postgres driver to communicate with what I believe is an encrypting server (at least according to pgadmin).  I did lots of things, such as building the driver from source, that might have been critical, but I strongly suspect that the key to success was simply using ServerName in place of Server in .odbc.ini.

FWIW.

Bill